全文获取类型
收费全文 | 6028篇 |
免费 | 337篇 |
国内免费 | 1916篇 |
专业分类
安全科学 | 503篇 |
废物处理 | 337篇 |
环保管理 | 487篇 |
综合类 | 3328篇 |
基础理论 | 1019篇 |
污染及防治 | 1858篇 |
评价与监测 | 230篇 |
社会与环境 | 257篇 |
灾害及防治 | 262篇 |
出版年
2024年 | 4篇 |
2023年 | 77篇 |
2022年 | 284篇 |
2021年 | 238篇 |
2020年 | 181篇 |
2019年 | 192篇 |
2018年 | 200篇 |
2017年 | 277篇 |
2016年 | 276篇 |
2015年 | 331篇 |
2014年 | 406篇 |
2013年 | 604篇 |
2012年 | 473篇 |
2011年 | 589篇 |
2010年 | 396篇 |
2009年 | 382篇 |
2008年 | 475篇 |
2007年 | 407篇 |
2006年 | 389篇 |
2005年 | 267篇 |
2004年 | 191篇 |
2003年 | 234篇 |
2002年 | 189篇 |
2001年 | 151篇 |
2000年 | 162篇 |
1999年 | 142篇 |
1998年 | 117篇 |
1997年 | 129篇 |
1996年 | 94篇 |
1995年 | 101篇 |
1994年 | 69篇 |
1993年 | 75篇 |
1992年 | 61篇 |
1991年 | 47篇 |
1990年 | 29篇 |
1989年 | 9篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 1篇 |
排序方式: 共有8281条查询结果,搜索用时 15 毫秒
11.
Hai Zhao Dexiang Zhang Fangfang Wang Tingting Wu Jinsheng Gao 《Process Safety and Environmental Protection》2008,86(6):448-454
Fe–Mn oxide and Ce-doped Fe–Mn oxide sorbents were studied on the structural and desulfurization behavior in COS removal from syngas. The effects of cerium oxide on the Fe–Mn oxides have been investigated by XRD, BET, TPR, XPS and TEM methods. Analysis data show that the Ce-doped sorbent has larger specific surface area and better particles’ dispersion compared with non-modified Fe–Mn sorbent. The addition of Ce improves the reduction performance of Fe–Mn species. The desulfurization experiments show that the desulfurization activity of sorbent can be increased because of the promotion of the structural and redox properties by ceria doped. The Ce-doped sorbent can reduce COS from 15,000 ppmv to less than 0.1 ppmv at 325 °C and a space velocity of 1000 h−1. 相似文献
12.
考察了粒状胺丙基硅(CUNAX00X)对水溶液中微囊藻毒素-LR(mLR)和微囊藻毒素-LA(mLA)的等温吸附行为,并通过对胺丙基硅结构中的微孔尺寸分布特征、表面官能团--胺丙基团(-CH2CH2CH2NH 3)和羟基自由基(·OH)的红外分析,对吸附机制进行了初步探讨.结果表明,胺丙基硅通过物理吸附和化学吸附对水溶液中的mLR和mLA进行吸附,即胺丙基硅结构中的有效吸附微孔对mLR/mLA的物理吸附,固体表面离子化的胺丙基团和·OH与mLR/mLA分子结构中离子化的羧基(-COO-)以及pH=4.33条件下mLR分子结构中离子化的胍基(-NHCNH·NH 2)之间的弱离子吸附. 相似文献
13.
14.
以太阳光为实验光源研究了氯苯嘧啶醇在水溶液中的光解,考察了pH、水体类型、溶解氧及卤素离子等对其光解的影响.结果表明,氯苯嘧啶醇在水溶液中的光解符合一级动力学方程,在不同水体中氯苯嘧啶醇光解的速率大小顺序为:重蒸水>水库水>湖水>池塘水;氯苯嘧啶醇光解的半衰期随着溶液pH的增大而延长,当pH为5、7、9、11时光解半衰期分别为5.00、6.86、7.45、7.53 h;3种卤素离子对氯苯嘧啶醇光解有很大的影响,均表现出强的猝灭作用,3种离子的猝灭能力的大小顺序为Ⅰ->Br->Cl-;溶解氧和三重态光猝灭剂山梨酸均对氯苯嘧啶醇在水中的光解没有影响,而三重态光敏剂丙酮则对其光解有较强的猝灭作用,表明氯苯嘧啶醇在水中的光解主要以直接光解为主,光解过程不经历三重态. 相似文献
15.
我国海岸侵蚀灾害及对策 总被引:1,自引:0,他引:1
文章通过大量实际资料展现了我国海岸侵蚀灾害的严重性;从入海泥沙、人类活动、地面沉降、海岸特性、海平面上升等方面分析了造成海岸侵蚀的原因;提出了一系列防治海岸侵蚀灾害的对策。 相似文献
16.
17.
Environment, Development and Sustainability - Sustainability assessing on agricultural production systems has developed rapidly over the last two decades, and various models are formulated from... 相似文献
18.
沟道土地是陕北黄土丘陵沟壑区重要的土地资源。然而,当前对黄土高原沟道土地的盐碱化问题关注不够,对盐碱化的现状、发生机制和防治措施也缺乏深入系统的认识,知识储备不能满足生产实际的需要。本文以陕北黄土丘陵沟壑区自然和人为形成的沟道土地为研究对象,分别是延安顾屯新造耕地(治沟造地)、延川马家湾淤地坝土地和子洲黄土洼天然古聚湫土地,在这些流域内沿沟道采集土壤样品,测定土壤的电导率(EC)、p H值、含水量及粒度,分析土壤盐碱化的现状和影响因子。结果表明:马家湾淤地坝土地盐碱化最为严重,流域中游至上游均出现不同程度的盐碱化;顾屯新造地上游出现盐碱化,盐碱化程度较马家湾轻,而黄土洼古聚湫全流域未出现盐碱化。地下水位较浅是沟道土地发生盐碱化的主要影响因素,因此陕北沟道土地盐碱化防治应着力控制地下水位,建设良好的排水系统,加强排水。 相似文献
19.
Influence of environmental factors on arsenic accumulation and biotransformation using the aquatic plant species Hydrilla verticillata 总被引:1,自引:0,他引:1
Hydrilla verticillata(waterthyme) has been successfully used for phytoremediation in arsenic(As) contaminated water.To evaluate the effects of environmental factors on phytoremediation,this study conducted a series of orthogonal design experiments to determine optimal conditions,including phosphorus(P),nitrogen(N),and arsenate(As(Ⅴ))concentrations and initial pH levels,for As accumulation and biotransformation using this aquatic plant species,while also analyzing As species transformation in culture media after 96-hr exposure.Analysis of variance and the signal-to-noise ratio were used to identify both the effects of these environmental factors and their optimal conditions for this purpose.Results indicated that both N and P significantly impacted accumulation,and N was essential in As species transformation.High N and intermediate P levels were critical to As accumulation and biotransformation by H.verticillata,while high N and low P levels were beneficial to As species transformation in culture media.The highest total arsenic accumulation was(197.2±17.4) μg/g dry weight when As(V) was at level 3(375μg/L),N at level 2(4 mg/L),P at level 1(0.02 mg/L),and pH at level 2(7).Although H.verticillata is highly efficient in removing As(Ⅴ) from aquatic environments,its use could be potentially harmful to both humans and the natural environment due to its release of highly toxic arsenite.For cost-effective and ecofriendly phytoremediation of As-contaminated water,both N and P are helpful in regulating As accumulation and transformation in plants. 相似文献
20.
Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH3 and NO react to produce N2 and H2O follows an Eley-Rideal type mechanism. NH2NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H2O, SO2 and metal on SCR catalysts were also summarized. 相似文献